| Cited as algin in some literature, the alginates cover a wide range of products, from the alginic acid to its salts (sodium, potassium, ammonium, magnesium and calcium alginates) and esters (propylene glycol alginate). |
| Since the discovery of alginates by
Edward Stanford in 1883, commercial production which started in 1927 has now expanded to
some 40,000 tonnes per year, world-wide. 30% of this tonnage is devoted to the food
industry, the rest being used in industrial, pharmaceutical and dental applications.
Alginate production is situated in California, the British Isles, Norway, France, Chile,
Japan and China. Alginates are extracted from various species of brown seaweeds (Phaecohyceae) by a multi-step process. A typical extraction process involves first washing and treating seaweed with diluted sulfuric acid (quantitively transforming calcium alginate into alginic acid), extraction by dissolution with alkali, separation of insolubles, then precipitation as the calcium salt, followed by acid washing to recover alginic acid. The salts and esters of alginic acids are obtained by neutralisation and esterification, respectively. Alginates are polysaccharides consisting of mannuronic and guluronic acid units. Many toxicological and metabolic studies in both animals and humans have proved their safety as food additives. Food grade quality alginates comply with relevant international and national purity specifications. Alginic acid, its sodium, potassium, ammonium and calcium salts, and propylene glycol alginate have been given INS numbers of 400 to 405 (E400 to E405 in the EU) To meet the varied needs of customers a range of product grades are available with differing viscosities, gelling properties and particle sizes. |
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| The
thickening and stabilising properties of alginates are illustrated by their use in fruit
drinks, salad dressings, milk shakes and sauces. Their gelling properties have found
unique application in restructured foods, bakery fillings, dessert gels and pet foods. Due
to its interaction with proteins, propylene glycol alginate is also successfully used as a
foam stabiliser in beer and cider. Alginates are also widely used in pharmaceutical and industrial applications. |
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